Hi Chris
If you purchase Creative Cloud for Teams you will be able to manage the licenses via the Admin Console. Currently, single app plans for Teams are only available via resellers so they would be able to help you if you wanted to order a mix of complete Creative Cloud & single apps for Teams:
Cloud technology | Adobe Creative Cloud for small & medium business
Thanks
Bev
EDIT - if you're looking to order 5 seats or more, our Sales team can assist - 0800 3892041