As far as I know only some special Wacom pens support rotate, Most pens do not. Even Pen tilt seems to lock down once the pen touches the tablets surface. As fare as I know Photoshop has no special support for 3D mice. Photoshop CC 2014 has some experimental touch support for windows touch gestures like rotate. and Mac has enable gesture. Pen rotate and gesture rotate are different one rotate the canvas like you do drawing on paper. the other rotate the brush tip. Rotate also requires a enabled GPU.
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